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Optimal slot dimension for skirt support structure of coke drums

Edward WANG, Zihui XIA

《机械工程前沿（英文）》 2018年 第13卷 第4期   页码 554-562 doi: 10.1007/s11465-018-0513-y

摘要：

The skirt-to-shell junction weld on coke drums is susceptible to fatigue failure due to severe thermal cyclic stresses. One method to decrease junction stress is to add slots near the top of the skirt, thereby reducing the local stiffness close to the weld. The most common skirt slot design is thin relative to its circumferential spacing. A new slot design, which is significantly wider, is proposed. In this study, thermal-mechanical elastoplastic 3-D finite element models of coke drums are created to analyze the effect of different skirt designs on the stress/strain field near the shell-to-skirt junction weld, as well as any other critical stress locations in the overall skirt design. The results confirm that the inclusion of the conventional slot design effectively reduces stress in the junction weld. However, it has also been found that the critical stress location migrates from the shell-to-skirt junction weld to the slot ends. A method is used to estimate the fatigue life near the critical areas of each skirt slot design. It is found that wider skirt slots provide a significant improvement on fatigue life in the weld and slot area.

关键词： coke drum     stress analysis     cyclic stress     fatigue life     skirt slots    

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Design and application of a novel coal-fired drum boiler using saline water in heavy oil recovery

Junping GU, Yuxin WU, Liping WU, Man ZHANG, Hairui YANG, Junfu LYU

《能源前沿（英文）》 2020年 第14卷 第4期   页码 715-725 doi: 10.1007/s11708-020-0690-3

摘要： In this paper, the design and operation of a novel coal-fired circulating fluidized bed (CFB) drum boiler that can generate superheated steam using saline water were introduced. The natural circulation water dynamics with a drum was adopted instead of the traditional once-through steam generator (OTSG) design, so that superheated steam can be generated for the better performance of the steam assisted gravity drainage (SAGD) technology in heavy oil recovery. The optimized staged evaporation method was proposed to further decrease the salinity of water in the clean water section of the boiler. The evaporating pipes of the salted water section were rearranged in the back pass of the boiler, where the heat load is low, to further improve the heat transfer safety. A CFB combustion technology was used for coal firing to achieve a uniform heat transfer condition with low heat flux. Pollutant control technologies were adopted to reduce pollutant emissions. Based on the field test, the recommended water standard for the coal-fired CFB drum boilers was determined. With the present technology, the treated recovery wastewater can be reused in steam-injection boilers to generate superheated steam. The engineering applications show that the boiler efficiency is higher than 90%, the blowdown rate is limited within 5.5%, and the superheat of steam can reach up to 30 K. Besides, the heavy oil recovery efficiency is significantly improved. Moreover, the pollutant emissions of SO , NO and dust are controlled within the ranges of 20–90 mg/(N·m ), 30–90 mg/(N·m ) and 2–10 mg/(N·m ) respectively.

关键词： drum steam injection boiler     natural circulation     recovery wastewater     staged evaporation     circulating fluidized bed (CFB)    

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Refrigeration cycle for cryogenic separation of hydrogen from coke oven gas

CHANG Kun, LI Qiang

《能源前沿（英文）》 2008年 第2卷 第4期   页码 484-488 doi: 10.1007/s11708-008-0096-0

摘要： Ten billion cubic meters of hydrogen are dissipated to the environment along with the emission of coke-oven gas every year in China. A novel cryogenic separation of hydrogen from coke oven gas is proposed to separate the hydrogen and liquefy it simultaneously, and the cooling capacity is supplied by two refrigeration cycles. The performance of the ideal vapor refrigeration cycle is analyzed with methane and nitrogen as refrigerant respectively. The results show that the coefficient of performance (COP) of methane refrigeration cycle is 2.7 times that of nitrogen refrigeration cycle, and the figure of merit (FOM) of methane refrigeration cycle is 1.6 times that of nitrogen refrigeration cycle. The performance of ideal gas refrigeration cycle is also analyzed with neon, hydrogen and helium as refrigerant respectively. The results show that both the coefficient of performance and figure of merit of neon refrigeration cycle is the highest. It is thermodynamically possible to arrange the refrigeration cycle with methane and neon as refrigerant, respectively.
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Comparison of combustion characteristics of petroleum coke and coal in one-dimensional furnace

Qulan ZHOU, Qinxin ZHAO, Guangjie ZHOU, Huiqing WANG, Tongmo XU, Shien HUI,

《能源前沿（英文）》 2010年 第4卷 第3期   页码 436-442 doi: 10.1007/s11708-009-0059-0

摘要： The effect of primary air fraction , outer secondary air swirl strength and excess oxygen coefficient on the combustion characteristics of petroleum coke, Hejin lean coal and Shenmu soft coal are researched on a one-dimensional furnace using a dual channel swirl burner. The results show that with the increase in primary air fraction , the NO emission concentrations of both Hejin lean coal and petroleum coke increase, and the combustion worsens in the earlier stage, but the burn-out rate of Shenmu soft coal is improved. The NO emission concentration obtains a minimum value with an increase in . The ignition and burn-out rate of petroleum coke and Shenmu soft coal are optimal when Ω is minimum and Ω=0.87, respectively. However, both the NO emission concentration of petroleum coke and Shenmu soft coal are minimum when Ω=1.08. The increase in excess oxygen coefficient delays the ignition of petroleum coke, worsens the combustion condition and increases the NO emission concentration, but it greatly decreases the NO emission concentration of Shenmu soft coal.

关键词： petroleum coke     Shenmu soft coal     Hejin lean coal     combustion characteristics     experimental research    

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Optimization of process parameters for preparation of powdered activated coke to achieve maximum SO

Binxuan ZHOU, Tao WANG, Tianming XU, Cheng LI, Yuan ZHAO, Jiapeng FU, Zhen ZHANG, Zhanlong SONG, Chunyuan MA

《能源前沿（英文）》 2021年 第15卷 第1期   页码 159-169 doi: 10.1007/s11708-020-0719-7

摘要： Powdered activated coke (PAC) is a good adsorbent of SO , but its adsorption capacity is affected by many factors in the preparation process. To prepare the PAC with a high SO adsorption capacity using JJ-coal under flue gas atmosphere, six parameters (oxygen-coal equivalent ratio, reaction temperature, reaction time, O concentration, CO concentration, and H O concentration) were screened and optimized using the response surface methodology (RSM). The results of factor screening experiment show that reaction temperature, O concentration, and H O (g) concentration are the significant factors. Then, a quadratic polynomial regression model between the significant factors and SO adsorption capacity was established using the central composite design (CCD). The model optimization results indicate that when reaction temperature is 904.74°C, O concentration is 4.67%, H O concentration is 27.98%, the PAC (PAC-OP) prepared had a higher SO adsorption capacity of 68.15 mg/g while its SO adsorption capacity from a validation experiment is 68.82 mg/g, and the error with the optimal value is 0.98%. Compared to two typical commercial activated cokes (ACs), PAC-OP has relatively more developed pore structures, and its and are 349 m /g and 0.1475 cm /g, significantly higher than the 186 m /g and 0.1041 cm /g of AC1, and the 132 m /g and 0.0768 cm /g of AC2. Besides, it also has abundant oxygen-containing functional groups, its surface O content being 12.09%, higher than the 10.42% of AC1 and 10.49% of AC2. Inevitably, the SO adsorption capacity of PAC-OP is also significantly higher than that of both AC1 and AC2, which is 68.82 mg/g versus 32.53 mg/g and 24.79 mg/g, respectively.

关键词： powdered activated coke (PAC)     SO2 adsorption capacity     parameters optimization     response surface methodology    

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Formation of coke in thermal cracking of jet fuel under supercritical conditions

ZHU Yuhong, YU Caixiang, LI Zimu, MI Zhentao, ZHANG Xiangwen

《化学科学与工程前沿（英文）》 2008年 第2卷 第1期   页码 17-21 doi: 10.1007/s11705-008-0024-1

摘要： Continuous-flow reactor experiments were carried out to study coke formation from thermal cracking of home-made jet fuel RP-3 under supercritical conditions. The mechanism and precursor of coke forming were analyzed. The starting cracking temperature of RP-3 fuel was determined to be 471.8°C by differential scanning calorimetry (DSC). Temperature-programmed oxidation and scanning electron microscopy (SEM) characterizations of the stressed tubes showed that there are three different coke species including chemisorbed carbon, amorphous carbon and filamentous coke in the solid deposits. More than 90% of coke deposits are carried away by the supercritical fluid, which has strong capabilities of extraction for coke deposits and their precursors. There were 17.1 wt-% of iron and 11.1 wt-% of chromium found on the coke surface detected by energy dispersive spectroscopy (EDS) which suggests carburetion on alloy. RP-3 fuel and its cracking liquids were analyzed by GC-MS,which showed that the content of alkyl benzene and alkyl naphthalene increased evidently in cracking liquids.

关键词： dispersive spectroscopy     different     extraction     calorimetry     filamentous    

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Sensitivity analysis of a methanol and power polygeneration system fueled with coke oven gas and coal

Guoqiang ZHANG, Lin GAO, Hongguang JIN, Rumou LIN, Sheng LI

《化学科学与工程前沿（英文）》 2010年 第4卷 第4期   页码 491-497 doi: 10.1007/s11705-010-0511-z

摘要： The sensitivity analysis of a polygeneration energy system fueled with duo fuel of coke oven gas and coal gas is performed in the study, and the focus is put on the relations among syngas composition, conversation rate and performance. The impacts of the system configuration together with the fuel composition on the performance are investigated and discussed from the point of cascading utilization of fuel chemical energy. First, the main parameters affecting the performance are derived along with the analysis of the system configuration and the syngas composition. After the performance is being simulated by means of the Aspen Plus process simulator of version 11.1, the variation of the performance due to the composition of syngas and the conversion rate of chemical subsystem is obtained and discussed. It is obtained from the result that the proper conversion rate of the chemical subsystem according to the specific syngas composition results in better performance. And the syngas composition affects the optimal conversion rate of the chemical subsystem, the optimal point of which is around the stoichiometric composition for methanol production (CO/H = 0.5). In all, the polygeneration system fueled with coke oven gas and coal gas, which can realize the reasonable conversion of syngas to power and chemical product according to the syngas composition, is a promising method for coal energy conversion and utilization.

关键词： duo fuel of coke oven gas and coal gas     polygeneration of power and methanol     sensitivity analysis     the relation among energy utilization     syngas composition and chemical conversion rate    

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Effect of oil shale semi-coke on deposit mineralogy and morphology in the flue path of a CFB burning

Zhuo LIU, Jianbo LI, Mingming ZHU, Xiaofeng LU, Zhezi ZHANG, Dongke ZHANG

《能源前沿（英文）》 2021年 第15卷 第1期   页码 26-37 doi: 10.1007/s11708-020-0668-1

摘要： The effect of oil shale semi-coke (SC) on the mineralogy and morphology of the ash deposited on probes situated in the flue path of a circulating fluidized bed (CFB) which burns Zhundong lignite (ZD) was investigated. 10 wt% or 20 wt% SC was added to ZD, which were then combusted in the CFB furnace at 950°C. Two probes with vertical and horizontal orientations were installed in the flue duct to simulate ash deposition. Both windward and leeward ash deposits on probes (P W, P L, P W and P L) were analyzed by using a scanning electron microscopy with energy dispersive X-ray (SEM-EDX), X-ray diffraction (XRD), an inductively coupled plasma optical emission spectrometry ICP-OES, and a particle size analyzer. When ZD was burned alone, the P W deposit was comprised of agglomerates (<30 m) enriched in CaSO and Na SiO , incurring significant sintering. The P L and P W deposits, however, were of both discrete and agglomerated particles in similar mineral phases but with coarser sizes. The P L deposit was mainly fine ash particles where Na SiO and Na SO were absent. As SC was added, the agglomerates in both P W and P L decreased. Moreover, SiO and Ca/Na aluminosilicates dominated the mineral phases whereas Na SiO and Na SO disappeared, showing a decrease in deposit stickiness. Likewise, the P W deposit was found less spread on the probe, decreasing its deposition propensity. Na-bearing minerals turned into (Na, K)(Si Al)O and (Ca, Na)(Si, Al) O in the P W deposit. Moreover, Na in the deposits decreased from 32 mg/g to less than 15 mg/g as SC presented. The addition of SC would therefore help alleviate the propensity of ash deposition in the flue path in the CFB combustion of ZD.

关键词： ash deposition     circulating fluidized bed (CFB)     mineral transformation     oil shale semi-coke (SC)     Zhundong lignite (ZD)    

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Catalytic performance of Co-Mo-Ce-K/γ-Al

Yuqiong ZHAO, Yongfa ZHANG

《化学科学与工程前沿（英文）》 2010年 第4卷 第4期   页码 457-460 doi: 10.1007/s11705-010-0524-7

摘要： The catalytic performance of Co-Mo-Ce-K/γ-Al O catalyst for the shift reaction of CO in coke oven gas is investigated using X-ray diffraction (XRD) and temperature-programmed reduction (TPR). The results indicate that Ce and K have a synergistic effect on promoting the catalytic activity, and the Co-Mo-Ce-K/γ-Al O catalyst with 3.0 wt-% CeO and 6.0 wt-% K O exhibits the highest activity. CeO favors Co dispersion and mainly produces an electronic effect. TPR characterization results indicate that the addition of CeO -K O in the Co-Mo-Ce-K/γ-Al O catalyst decreases the reduction temperature of active components, and part of octahedrally coordinated Mo transforms into tetrahedrally coordinated Mo , which has a close relationship with the catalytic activity.

关键词： coke oven gas     water gas shift reaction     sulfur-tolerant catalyst     cerium dioxide    

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Effect of temperature in the conversion of methanol to olefins (MTO) using an extruded SAPO-34 catalyst

Ignacio Jorge Castellanos-Beltran, Gnouyaro Palla Assima, Jean-Michel Lavoie

《化学科学与工程前沿（英文）》 2018年 第12卷 第2期   页码 226-238 doi: 10.1007/s11705-018-1709-8

摘要： The methanol-to-olefin (MTO) reaction was investigated in a bench-scale, fixed-bed reactor using an extruded catalyst composed of a commercial SAPO-34 (65 weight percentage, wt-%) embedded in an amorphous SiO matrix (35 wt-%). The texture properties, acidity and crystal structure of the pure SAPO-34 and its extruded form (E-SAPO-34) were analyzed and results indicated that the extrusion step did not affect the properties of the catalyst. Subsequently, E-SAPO-34 was tested in a temperature range between 300 and 500 °C, using an aqueous methanol mixture (80 wt-% water content) fed at a weight hour space velocity (WHSV) of 1.21 h . At 300 °C, a low conversion was observed combined with catalyst deactivation, which was ascribed to oligomerization and condensation reactions. The coke analysis showed the presence of diamandoid hydrocarbons, which are known to be inactive molecules in the MTO process. At higher temperatures, a quasi-steady state was reached during a 6 h reaction where the optimal temperature was identified at 450 °C, which incidentally led to the lowest coke deposition combined with the highest H/C ratio. Above 450 °C, surges of ethylene and methane were associated to a combination of H-transfer and protolytic cracking reactions. Finally, the present work underscored the convenience of the extrusion technique for testing catalysts at simulated scale-up conditions.

关键词： MTO     SAPO-34     temperature     extrusion     coke     light alkanes    

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A review on co-pyrolysis of coal and oil shale to produce coke

Xiangchun Liu, Ping Cui, Qiang Ling, Zhigang Zhao, Ruilun Xie

《化学科学与工程前沿（英文）》 2020年 第14卷 第4期   页码 504-512 doi: 10.1007/s11705-019-1850-z

摘要： It has become the top priority for coking industry to rationally use and enlarge coking coal resources because of the shortage of the resources. This review focuses on the potential utilization of oil shale (OS) as a feedstock for coal-blending coking, in which the initial and basic step is pyrolysis. However, OS has a high ash content. If such OS is directly used for coal-blending coking, the coke product will not meet market demand. Therefore, this review firstly summarizes separation and beneficiation techniques for organic matter in OS, and provides an overview on coal and OS pyrolysis through several viewpoints (e.g., pyrolysis process, phenomena, and products). Then the exploratory studies on co-pyrolysis of coal with OS, including co-pyrolysis phenomena and process mechanism, are discussed. Finally, co-pyrolysis of different ranks of coals with OS in terms of coal-blending coking, where further research deserves to be performed, is suggested.

关键词： coal     oil shale     co-pyrolysis     coal blending coking     coke    

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of light gas oil using a NiMo catalyst supported on activated carbon produced from fluid petroleum coke

N. Rambabu,Sandeep Badoga,Kapil K. Soni,A.K. Dalai,J. Adjaye

《化学科学与工程前沿（英文）》 2014年 第8卷 第2期   页码 161-170 doi: 10.1007/s11705-014-1430-1

摘要： Nitric acid functionalized steam activated carbon (NAFSAC) was prepared from waste fluid petroleum coke (FPC) and used as a support material for the synthesis of a NiMo catalyst (2.5 wt-% Ni and 13 wt-% Mo). The catalyst was then used for the hydrotreatment of light gas oil. The support and catalysts were characterized by Brunauer-Emmett-Teller (BET) gas adsorption method, X-ray diffraction, H -temperature programmed reduction, NH -temperature programmed desorption, CO-chemisorption, mass spetrography, scanning electron microscopy (SEM), Boehm titration, and Fourier transform infrared spectroscopy (FTIR). The SEM results showed that the carbon material retained a needle like structure after functionalization with HNO . The Boehm titration, FTIR, and BET results confirmed that the HNO functionalized material had moderate acidity, surface functional groups, and mesoporosity respectively. The produced NAFSAC had an inert nature, exhibited the sink effect and few metal support interactions, and contained functional groups. All of which make it a suitable support material for the preparation of a NiMo hydrotreating catalyst. Hydrotreating activity studies of the NiMo/NAFSAC catalyst were carried out under industrial operating conditions in a laboratory trickle bed reactor using coker light gas oil as the feedstock. A parallel study was performed on the hydrotreating activity of NiMo/ -Al O as a reference catalyst. The hydrodesulfurization and hydrodenitrogenation activities of the NiMo/NAFSAC catalyst were 62% and 30%, respectively.

关键词： activated carbon     fluid petroleum coke     NiMo catalyst     hydrotreating     light gas oil    

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标题 作者 时间 类型 操作

Optimal slot dimension for skirt support structure of coke drums

Edward WANG, Zihui XIA

期刊论文

Design and application of a novel coal-fired drum boiler using saline water in heavy oil recovery

Junping GU, Yuxin WU, Liping WU, Man ZHANG, Hairui YANG, Junfu LYU

期刊论文

Refrigeration cycle for cryogenic separation of hydrogen from coke oven gas

CHANG Kun, LI Qiang

期刊论文

Comparison of combustion characteristics of petroleum coke and coal in one-dimensional furnace

Qulan ZHOU, Qinxin ZHAO, Guangjie ZHOU, Huiqing WANG, Tongmo XU, Shien HUI,

期刊论文

Optimization of process parameters for preparation of powdered activated coke to achieve maximum SO

Binxuan ZHOU, Tao WANG, Tianming XU, Cheng LI, Yuan ZHAO, Jiapeng FU, Zhen ZHANG, Zhanlong SONG, Chunyuan MA

期刊论文

Formation of coke in thermal cracking of jet fuel under supercritical conditions

ZHU Yuhong, YU Caixiang, LI Zimu, MI Zhentao, ZHANG Xiangwen

期刊论文

Sensitivity analysis of a methanol and power polygeneration system fueled with coke oven gas and coal

Guoqiang ZHANG, Lin GAO, Hongguang JIN, Rumou LIN, Sheng LI

期刊论文

Effect of oil shale semi-coke on deposit mineralogy and morphology in the flue path of a CFB burning

Zhuo LIU, Jianbo LI, Mingming ZHU, Xiaofeng LU, Zhezi ZHANG, Dongke ZHANG

期刊论文

Catalytic performance of Co-Mo-Ce-K/γ-Al

Yuqiong ZHAO, Yongfa ZHANG

期刊论文

Effect of temperature in the conversion of methanol to olefins (MTO) using an extruded SAPO-34 catalyst

Ignacio Jorge Castellanos-Beltran, Gnouyaro Palla Assima, Jean-Michel Lavoie

期刊论文

A review on co-pyrolysis of coal and oil shale to produce coke

Xiangchun Liu, Ping Cui, Qiang Ling, Zhigang Zhao, Ruilun Xie

期刊论文

of light gas oil using a NiMo catalyst supported on activated carbon produced from fluid petroleum coke

N. Rambabu,Sandeep Badoga,Kapil K. Soni,A.K. Dalai,J. Adjaye

期刊论文